| Title | Season | Episode # | First Aired |
|---|---|---|---|
| Secrets of a Successful Marriage | 5 | 22 | Thursday May 19, 1994 |
| See Homer Run | 17 | 6 | Sunday November 20, 2005 |
| Selma's Choice | 4 | 13 | Thursday January 21, 1993 |
| Separate Vocations | 3 | 18 | Thursday February 27, 1992 |
| Sex, Pies and Idiot Scrapes | 20 | 1 | September 28, 2008 |
| She of Little Faith | 13 | 6 | Sunday December 16, 2001 |
| She Used to Be My Girl | 16 | 4 | Sunday December 5, 2004 |
| Sideshow Bob Roberts | 6 | 5 | Sunday October 9, 1994 |
| Sideshow Bob's Last Gleaming | 7 | 9 | Sunday November 26, 1995 |
| Simple Simpson | 15 | 19 | Sunday May 2, 2004 |
| Simpson and Delilah | 2 | 2 | Thursday October 18, 1990 |
| Simpson Safari | 12 | 17 | Sunday April 1, 2001 |
| Simpson Tide | 9 | 19 | Sunday March 29, 1998 |
| Simpsoncalifragilisticexpiala(Annoyed Grunt)cious | 8 | 13 | Friday February 7, 1997 |
| Simpsons Bible Stories | 10 | 18 | Sunday April 4, 1999 |
| Simpsons Christmas Stories | 17 | 9 | Sunday December 18, 2005 |
| Simpsons Roasting on an Open Fire | 1 | 1 | Sunday December 17, 1989 |
| Simpsons Tall Tales | 12 | 21 | Sunday May 20, 2001 |
| Skinner's Sense of Snow | 12 | 8 | Sunday December 17, 2000 |
| Sleeping with the Enemy | 16 | 3 | Sunday November 21, 2004 |
| Smart and Smarter | 15 | 13 | Sunday February 22, 2004 |
| Smoke on the Daughter | 19 | 15 | Sunday March 30, 2008 |
| So It's Come to This: A Simpsons Clip Show | 4 | 18 | Thursday April 1, 1993 |
| Some Enchanted Evening | 1 | 13 | Sunday May 13, 1990 |
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